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Casein

Casein powder bowl with brass fittings 1930s Buttons made from Erinoid casein Galatix dressing table ware  
  Electrical and other components made from Erinoid casein Casein knitting needles Propelling pencils made from casein

Casein plastics were introduced at the beginning of the 20th century, their starting material being the protein in cows milk, precipitated by the action of the enzyme rennin.
Although casein is readily moulded to shape under moderate heat and pressure, it does not produce a stable material for manufacture until it has become hardened by soaking in formalin (5% solution of formaldehyde in water) for a long period. Unfortunately, this causes much distortion so casein plastics are almost always produced by machining stock material such as sheet, rod, tube or buttton blanks (small discs). After machining, casein may be polished either mechanically with abrasives or chemically with a 'dip polish'.
The material readily takes a surface dye, so coloured items can be quickly made from pale coloured stock items. This was especially important for the button trade which was the principal consumer of casein plastics.
As well as buttons and buckles, casein was also used for knitting pins, fountain pen and propelling pencil barrels, dressing table ware and a host of other items.

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