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ABS

     

The structure of ABS is based on 3 monomers - acrylonitrile, butadiene and styrene. It is therefore defined as a terpolymer. Its manufacture is essentially based on the graft polymerisation of polybutadiene latex (the rubbery phase) with styrene acrylonitrile polymer (SAN the plastic phase). Varying the proportions of the three monomers, and the way in which they are combined, means that a wide spectrum of ABS plastics can be produced, with properties 'tailored' to meet specific requirements.
In addition to this great versatility, ABS plastics in general are distinguished by great toughness and high impact strength (even at low temperatures), good dielectric properties and excellent dimensional stability. To this is added extremely fine gloss appearance, very wide colouring possibilities and ready availability.
All these attributes mean that when ABS was introduced in the mid 1950s, plastics could for the first time offer real competition with many traditional materials such as metals, for making highly durable mouldings with great consumer appeal.
ABS was in fact the first 'engineering' thermoplastic and major outlets were soon found in the automotive industry, furniture (the Kartell one-piece chair) and especially in a huge variety of electrical and electronic appliances, from telephones to typewriters, calculators, adio-visual units and kitchen equipment.
Thermoforming extruded ABS sheet led to some spectacular uses, notably the body of the Citröen Méhari jeep-like car. Almost 145,000 were built between 1968 and 1987, easily a record for a plastics-bodied car. Not all applications were so massive: the first important European application was the famous Lego brick from Denmark.
Although now augmented by other engineering thermoplastics with more specific properties, (e.g. acetals, polycarbonates, thermoplastics polyesters, polyphenylene oxide, etc.) ABS remains a very important - and versatile! - plastics material.

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